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Neutralisation

Key Stage 3

Meaning

Neutralisation is a chemical reaction in which an acid and a base react to produce a neutral product.

About Neutralisation

Neutralisation can reduce the danger from a corrosive spill.
An acid can be neutralised by adding a base.
A base can be neutralised by adding an acid.
When there is a dangerous acid spill it is better to use an insoluble base to neutralise it than an alkali because if too much is used the insoluble base will not make the solution go above pH 7 but an alkali may neutralise and then replace the acid with another corrosive chemical with a high pH.
During neutralisation experiments an indicator is added to observe when the solution becomes neutral.

Examples

Hydrochloric Acid + Lithium OxideLithium Chloride + Water
Hydrochloric Acid + Iron OxideIron Chloride + Water
Sulphuric Acid + Potassium HydroxidePotassium Sulphate + Water
Sulphuric Acid + Aluminium HydroxideAluminium Sulphate + Water
Nitric Acid + Magnesium CarbonateMagnesium Nitrate + Carbon Dioxide + Water
Nitric Acid + Titanium CarbonateTitanium Nitrate + Carbon Dioxide + Water

Key Stage 4

Meaning

Neutralisation is a chemical reaction in which an acid and a base react to produce a neutral product.

About Neutralisation

The general equation for a neutralisation reaction is:
Acid + BaseSalt + Water
When a neutralisation reaction happens in solution the Hydrogen ions and Hydroxide ions react to form water.

Neutralising Acids

To neutralise an acid it is important to use the right amount of base or alkali to produce a neutral substance. Too much base or alkali and the solution will not be turned alkali instead of neutral.

An acid can be neutralised with:

Examples

2HCl(aq) + Li2O(s) → 2LiCl(aq) + H2O(l)
6HCl(aq) + Fe2O3(s) → 2FeCl3(aq) + 3H2O(l)
H2SO4(aq) + 2KOH(aq) → K2SO4(aq) + H2O(l)
3H2SO4(aq) + 2Al(OH)3(aq) → Al2(SO4)3(aq) + 6H2O(l)
2HNO3(aq) + MgCO3(s) → Mg(NO3)2(aq) + H2O(l)
2HNO3(aq) + TiCO3(s) → Ti(NO3)2(aq) + H2O(l)

References

AQA

Neutralisation, pages 116-7, 130-1, 142-3, 148-9, 150-1, 175, 175-7, GCSE Chemistry; Student Book, Collins, AQA
Neutralisation, pages 74-77, 92-97, 232-233, GCSE Chemistry; Third Edition, Oxford University Press, AQA