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Transition Metal

Key Stage 4

Meaning

Transition Metals (also known as transition elements) are a block of elements on the Periodic Table between Group 2 and Group 3.

About Transition Metals

Transition Metals have the physical properties of metals.
Transition Metals bond together with metallic bonds in which positive ions are surrounded by a sea of negatively charged electrons (known as delocalised electrons.
Transition metals
Period 4 21Sc 22Ti 23V 24Cr 25Mn 26Fe 27Co 28Ni 29Cu 30Zn
Period 5 39Y 40Zr 41Nb 42Mo 43Tc 44Ru 45Rh 46Pd 47Ag 48Cd
Period 6 57La 72Hf 73Ta 74W 75Re 76Os 77Ir 78Pt 79Au 80Hg
Period 7 89Ac 104Rf 105Db 106Sg 107Bh 108Hs 109Mt 110Ds 111Rg 112Cn

Melting Point

Transition Metals usually have high melting points because metallic bonds are very strong, keeping the atoms vibrating in fixed positions.
The transition metal melting points measured in Kelvin are written below each chemical symbol.
TransitionMetalMeltingPoints.png
N.B. The Period 7 elements have not been included as they do not occur naturally and have not been made in large enough quantities to find their melting points.

Density

Transition Metals have a high density compared to other elements. However, many of the Actinides also have a density.
The transition metal densities measured in kilograms per metre cubed are written below each chemical symbol.
TransitionMetalDensity.png
N.B. The Period 7 elements have not been included as they do not occur naturally and have not been made in large enough quantities to find their [density|densities]].

Reactivity

The Transition Metals are much less reactive than elements in group 1 and group 2.
Most of the Transition Metals react slowly with Oxygen, Water and the Halogens at room temperature and some will not react at all.
For combustion to occur the Transition Metals must be heated to very high temperatures. However, some Transition Metals will not combust at all.

Ion Formation

Transition Metals form positive ions during chemical reactions.
Transition Metals can form several different charge ions and these different charges can determine the physical properties of the compounds they are in. Specifically this affects the colour of those compounds.

In compounds the charge of the Transition Metal ion is given in Roman Numerals after the name of the metal

Gem stones with various colours (red rubies, green emeralds, blue sapphires) get their colour from the Transition Metal ions they contain.

Catalysts

Many Transition Metals can be used as catalysts for chemical reactions.
Catalysts can increase the rate of reaction and lower the temperature needed to start a reaction.
Catalysts are not used up in the chemical reaction so can be used over and over again.
Transition Metal catalysts can increase the rate of reaction by either accepting or donating electrons so that not as much energy is needed for a reaction to happen.

These are some Transition Metal catalysts you may know:

References

AQA

Transition metal, pages 48-9, GCSE Chemistry; Student Book, Collins, AQA
Transition metals, pages 18-19, GCSE Chemistry, Hodder, AQA
Transition metals, pages 23, 24, 25, GCSE Chemistry; The Revision Guide, CGP, AQA

Edexcel

Transition metals, page 62, GCSE Chemistry; The Revision Guide, CGP, Edexcel
Transition metals, pages 177, 178, GCSE Chemistry, CGP, Edexcel
Transition metals, pages 96-97, GCSE Chemistry, Pearson, Edexcel
Transition metals; chemical properties, page 97, GCSE Chemistry, Pearson, Edexcel
Transition metals; physical properties, pages 96-97, GCSE Chemistry, Pearson, Edexcel

OCR

Transition metals, page 55, Gateway GCSE Chemistry; The Revision Guide, CGP, OCR
Transition metals, pages 88, 140-141, Gateway GCSE Chemistry, Oxford, OCR